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灭菌磷_5131-24-8
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灭菌磷

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灭菌磷介绍:

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external7 accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.

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标准名称及标准号
GB/T 5750.9-2023《生活饮用水标准检验方法 第9部分:农药指标》
适用范围
适用于生活饮用水及其水源水中灭菌磷(CAS:5131-24-8)的检测,涵盖水样的采集、保存、前处理及仪器分析流程。
核心检测方法
采用气相色谱-质谱联用法(GC-MS)。水样经固相萃取(SPE)富集净化后,通过毛细管色谱柱分离,质谱检测器定性定量分析。
检出限与定量限
方法检出限(MDL)为0.02 μg/L,定量限(LOQ)为0.08 μg/L,满足饮用水卫生标准中关于灭菌磷的限量要求。
质控样品要求
每批次样品需包含空白对照、加标回收样品和平行样。加标浓度应为定量限的2-5倍,回收率需控制在70%-120%,相对标准偏差(RSD)≤15%。
关键实验步骤
1. 样品萃取:使用C18固相萃取柱,活化后上样,流速控制在3-5 mL/min;
2. 洗脱与浓缩:用5 mL乙酸乙酯洗脱,氮吹浓缩至0.5 mL;
3. 仪器条件:色谱柱为HP-5MS(30 m×0.25 mm×0.25 μm),进样口温度260℃,质谱扫描模式为SIM。
特别说明
1. 灭菌磷易光解,样品需避光保存并在48小时内完成前处理;
2. 若水样浑浊需先经0.45 μm滤膜过滤;
3. 质谱定性需满足保留时间偏差±2%内,特征离子丰度比与标准品一致。

以上信息仅供参考,请以相应标准的原文为准!