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克百威_1563-66-2,克百威
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克百威

BW902017 {{goodObj.price > 0 ? '¥' + goodObj.price : '咨询'}} ¥{{goodObj.sell_price || 0}} 咨询 1563-66-2 100mg {{goodObj.date}} 秦境 {{item.norm}} 98.6% {{inventory}}
克百威介绍:

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Product Name

Carbofuran

Product Code

BW902017

Lot Number

23051518

CAS No.

1563-66-2

Mol. Formula

C12H15NO3

Mol. Weight

221.25

Certified on

26 May 2023

Expiry Date

25 May 2025

Storage Temp

20°C ± 4°C

Specification

100 mg

CERTIFIED

Purity

CERTIFIED

Expanded Uncertainty (U)

Approved by

98.6%

0.5%

Method of Characterisation

GC/FID

Batch Information

Water Content: <0.1% (by Karl-Fischer-Titration)

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.


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标准名称及标准号
标准名称:食品安全国家标准 植物源性食品中灭多威、克百威、涕灭威及其代谢物残留量的测定 液相色谱法
标准号:GB 23200.113-2018
适用范围
适用于植物源性食品(如蔬菜、水果、谷物等)中克百威及其代谢物残留量的测定。适用基质包括新鲜或加工后的样品。
核心检测方法
1. 前处理:样品经乙腈提取,盐析分层后净化。
2. 仪器条件:高效液相色谱仪(HPLC)配备紫外检测器或二极管阵列检测器(DAD)。
3. 色谱条件:C18色谱柱(250 mm×4.6 mm, 5 μm),流动相为甲醇-水梯度洗脱,流速1.0 mL/min,检测波长210 nm。
检出限与定量限
检出限(LOD):0.005 mg/kg(以克百威计)。
定量限(LOQ):0.01 mg/kg(以克百威计)。
质控样品要求
1. 每批次样品需添加空白基质加标质控样,加标浓度为0.01 mg/kg。
2. 回收率范围要求为70%-120%。
3. 每20个样品中至少插入1个平行样,相对偏差≤20%。
关键实验步骤
1. 样品均质:样品需粉碎至粒径≤2 mm。
2. 提取:加入乙腈超声提取15 min,离心后取上清液。
3. 净化:使用PSA或C18固相萃取柱净化,洗脱液氮吹浓缩后用甲醇复溶。
4. 上机分析:按设定色谱条件进样,外标法定量。
特别说明
1. 克百威代谢物(3-羟基克百威)需同步检测,标准溶液需现配现用。
2. 需关注流动相的脱气及色谱柱平衡时间(≥30 min)。
3. 当样品基质复杂时,建议使用质谱法(LC-MS/MS)进行确证。

以上信息仅供参考,请以相应标准的原文为准!