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环己烷_110-82-7
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环己烷

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环己烷介绍:

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external7 accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.

Tel:029-85836892 Web:www.qjbzwz.com Email:qjbzwz@qjbzwz.com

Address:Jiawei Technology Industry Base, Aerospace East Road, Xi’an , Shaanxi Province


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1. 标准名称及标准号
标准名称:环境空气 挥发性有机物的测定 罐采样/气相色谱-质谱法
标准号:HJ 644-2013
2. 适用范围
本标准规定了环境空气中挥发性有机物(包括环己烷)的罐采样结合气相色谱-质谱联用(GC-MS)的检测方法,适用于环境空气和污染源无组织排放中挥发性有机物的测定。
3. 核心检测方法
使用惰性材质采样罐采集样品,经预浓缩仪富集后,通过气相色谱分离,质谱检测器进行定性和定量分析。环己烷在DB-5MS色谱柱中保留时间为5.3分钟,特征离子为84、55、56。
4. 检出限与定量限
环己烷的检出限为0.2 μg/m³(以采样体积100 L计),定量限为0.5 μg/m³。需根据实际采样体积调整计算结果。
5. 质控样品要求
每批次样品需至少包含1个实验室空白样和1个平行样。标准曲线相关系数需≥0.995,加标回收率应控制在80%-120%,否则需重新分析。
6. 关键实验步骤
(1) 使用经高温老化处理的采样罐,避免污染;
(2) 样品在预浓缩仪中去除水蒸气后富集;
(3) GC升温程序:初始40℃保持2分钟,以5℃/min升至120℃,再以10℃/min升至250℃;
(4) 质谱采用全扫描模式(Scan)或选择离子模式(SIM)采集数据。
7. 特别说明
环己烷易挥发且易燃,需在低温(<4℃)避光保存样品。分析前需确认色谱柱极性是否适用,避免与共流出物干扰。实验操作应符合实验室安全规范(如GB/T 27476)。

以上信息仅供参考,请以相应标准的原文为准!