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o,p'-DDT_789-02-6,2,4-DDT
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o,p'-DDT

BW902044 {{goodObj.price > 0 ? '¥' + goodObj.price : '咨询'}} ¥{{goodObj.sell_price || 0}} 咨询 789-02-6 10mg {{goodObj.date}} 秦境 {{item.norm}} 97.6% {{inventory}}
o,p’-DDT介绍:

REFERENCE MATERIAL CERTIFICATE

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Product Name

O,P’-DDT

Product Code

BW902044

Lot Number

23091505

CAS No.

789-02-6

Mol. Formula

C14H9Cl5

Mol. Weight

354.49

Certified on

2 Sep 2023

Expiry Date

1 Sep 2028

Storage Temp

20°C ± 4°C

Specification

10mg

CERTIFIED

Purity

CERTIFIED

Expanded Uncertainty (U)

Approved by

97.6%

1.0%

Method of Characterisation

GC/FID

Batch Information

Water Content: <0.1% (by Karl-Fischer-Titration)

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.


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标准名称及标准号
GB 23200.113-2018
食品安全国家标准 植物源性食品中208种农药及其代谢物残留量的测定 气相色谱-质谱联用法
适用范围
适用于植物源性食品中o,p'-DDT等有机氯类农药残留的定性及定量分析,包括谷物、蔬菜、水果等基质。
核心检测方法
1. 样品经乙腈提取,QuEChERS法净化
2. 气相色谱-质谱联用(GC-MS)分析
3. 采用选择离子监测模式(SIM)进行定量
检出限与定量限
检出限(LOD):0.005 mg/kg
定量限(LOQ):0.01 mg/kg(以样品干重计)
质控样品要求
1. 每批次样品需包含空白对照和加标回收样品
2. 加标浓度应覆盖定量限至10倍定量限范围
3. 回收率要求:70%-120%,相对标准偏差(RSD)≤15%
关键实验步骤
1. 样品均质后准确称量2.0 g
2. 加入乙腈震荡提取,离心分层
3. 取上清液经PSA和C18吸附剂净化
4. 氮吹浓缩后定容,GC-MS进样分析
特别说明
1. o,p'-DDT需与邻苯二甲酸酯类污染物分离
2. 实验过程中需严格避免塑料器皿污染
3. 色谱柱推荐使用DB-5MS(30 m×0.25 mm×0.25 μm)
4. 方法验证需符合GB/T 27404-2008要求

以上信息仅供参考,请以相应标准的原文为准!