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β-氯氰菊酯_1224510-29-5
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β-氯氰菊酯

BW902034 {{goodObj.price > 0 ? '¥' + goodObj.price : '咨询'}} ¥{{goodObj.sell_price || 0}} 咨询 1224510-29-5 80mg {{goodObj.date}} 秦境 {{item.norm}} 95.4% {{inventory}}
β-氯氰菊酯介绍:

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Method of Characterisation

GC/FID

Batch Information

Water Content: <0.10% (by Karl-Fischer-Titration)

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.

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标准名称及标准号
GB 23200.113-2018
《食品安全国家标准 植物源性食品中208种农药及其代谢物残留量的测定 气相色谱-质谱联用法》
适用范围
适用于植物源性食品中β-氯氰菊酯及其他207种农药残留的定量和定性分析,包括水果、蔬菜、谷物等样品基质。
核心检测方法
气相色谱-质谱联用法(GC-MS)。样品经乙腈提取后,通过QuEChERS法净化,采用选择离子监测模式(SIM)进行定量分析,内标法或外标法定量。
检出限与定量限
检出限(LOD)为0.005 mg/kg,定量限(LOQ)为0.01 mg/kg,具体取决于样品基质和干扰物情况。
质控样品要求
1. 空白样品加标回收率应在70%-120%;
2. 每批次样品需包含至少10%的平行样和加标样;
3. 使用有证标准物质进行校准曲线验证。
关键实验步骤
1. 样品均质后用乙腈振荡提取;
2. 使用PSA和C18吸附剂进行净化;
3. 氮吹浓缩后定容,过膜上机;
4. 色谱条件:DB-5MS毛细管柱,程序升温;
5. 质谱条件:EI源,监测特征离子(m/z 181, 163, 165)。
特别说明
1. β-氯氰菊酯易与基质中色素等干扰物共洗脱,需优化净化步骤;
2. 若样品中油脂含量高,需增加冷冻离心或GPC净化;
3. 标准溶液需避光保存,现用现配。

以上信息仅供参考,请以相应标准的原文为准!