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乙醇中4种酯类混标(GB/T 10345-2022)

BW06272 {{goodObj.price > 0 ? '¥' + goodObj.price : '咨询'}} ¥{{goodObj.sell_price || 0}} 咨询 1.2mL {{goodObj.date}} 秦境 {{item.norm}} 2500/25000μg/mL {{inventory}}
  • GR24

    C1896621 | >95%

  • S421

    N-13919-10MG | 见证书

  • Q203

    S82887-10mg | 98%

  • Q203

    S82887-1mg | 98%

  • Q203

    S82887-50mg | 98%

  • Q203

    S82887-5mg | 98%

乙醇中4种酯类混标

REFERENCE MATERIAL CERTIFICATE

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Product Name

3,4,5-Trichlorophenol

Product Code

BW901064

Lot Number

23061508

CAS No.

609-19-8

Mol. Formula

C6H3Cl3O

Mol. Weight

197.45

Certified on

2 Jun 2023

Expiry Date

1 Jun 2025

Storage Temp

20°C ± 4°C

Specification

25 mg

CERTIFIED

Purity

CERTIFIED

Expanded Uncertainty (U)

Approved by

98.6%

0.5%

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external7 accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.

相关标准解读:GB/T 10345-2022《白酒分析方法》

1. 适用范围

本标准规定了白酒中挥发性酯类物质(包括乙酸乙酯、己酸乙酯、乳酸乙酯、丁酸乙酯等)的检测方法,适用于以粮谷、薯类、水果等为原料酿造的白酒中酯类成分的定量分析。

2. 关联内容

检测对象: 乙醇基质中的酯类化合物(如用户提到的4种酯类混标)
方法原理: 采用气相色谱法(GC-FID或GC-MS)进行分离检测
前处理要求: 样品需经0.45 μm滤膜过滤,必要时进行稀释或浓缩处理
色谱条件: 规定了毛细管柱类型(如PEG-20M)、载气流速、程序升温条件等关键参数

3. 关键性能指标

酯类名称 检出限(mg/L) 定量限(mg/L)
乙酸乙酯 0.10 0.30
己酸乙酯 0.05 0.15
乳酸乙酯 0.20 0.60
丁酸乙酯 0.02 0.06

4. 方法验证要求

• 线性范围需覆盖待测物浓度的50%-150%
• 加标回收率应控制在85%-115%之间
• 同一样品6次平行测定的RSD≤5%

5. 注意事项

• 标准品配制应使用色谱纯乙醇作为溶剂基质
• 需定期进行色谱系统适应性试验(理论塔板数≥10000)
• 当样品中酯类总浓度超过5g/L时,建议稀释后测定

以上信息仅供参考,请以相应标准的原文为准!

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