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二氯乙酸_79-43-6,二氯乙酸
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二氯乙酸

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二氯乙酸介绍:

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external7 accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.

Reference Material Producer:Shaanxi Qinjing Reference Material Science and Technology Center

Tel:029-85836892 Web:www.qjbzwz.com Email:qjbzwz@qjbzwz.com

Address:Jiawei Technology Industry Base, Aerospace East Road, Xi’an , Shaanxi Province


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标准名称及标准号
国家标准名称 GB/T 5750.8-2023《生活饮用水标准检验方法 第8部分:有机物指标》
相关行业标准 GB 5009.278-2016《食品安全国家标准 食品中二氯乙酸的测定》
适用范围
GB/T 5750.8-2023 适用于生活饮用水中二氯乙酸等卤代有机酸的检测,覆盖水源水及处理后的饮用水。
GB 5009.278-2016 针对食品(如饮料、酱腌菜等)中二氯乙酸的测定,需结合样品前处理技术。
核心检测方法
方法类型 气相色谱-质谱联用法(GC-MS)或高效液相色谱法(HPLC)
原理 样品经衍生化处理后,通过色谱分离,质谱或紫外检测器定量分析二氯乙酸。
检出限与定量限
GB/T 5750.8-2023 检出限:0.5 μg/L;定量限:1.0 μg/L(水样)
GB 5009.278-2016 检出限:0.01 mg/kg;定量限:0.03 mg/kg(食品基质)
质控样品要求
空白实验 每批次样品需包含至少1个空白对照,确保无背景干扰。
加标回收率 回收率需控制在80%-120%,否则需重新测定。
关键实验步骤
水样前处理 酸化后用固相萃取柱富集,甲醇洗脱后氮吹浓缩至干,衍生化处理。
色谱条件 色谱柱:DB-5MS(30 m × 0.25 mm);升温程序:初始60℃保持2 min,以10℃/min升至250℃。
特别说明
干扰排除 若存在其他卤代酸干扰,需优化色谱条件或使用质谱选择离子监测模式(SIM)。
样品保存 水样采集后需4℃避光保存,48小时内完成前处理;食品样品需-20℃冷冻保存。

以上信息仅供参考,请以相应标准的原文为准!