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百菌清(EC 17025)_1897-45-6,百菌清
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百菌清(EC 17025)

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百菌清介绍:

Reference Material

This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO9001.


Method of Characterisation

GC/FID

Batch Information

Water Content: <0.1% (by Karl-Fischer-Titration)

Uncertainty

The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of characterisation, homogeneity and stability testing. Stability values are based on real evidence opposed to simulation.

The producer certifies that this reference material meets the specification stated in this certificate until the expiry date, provided it is stored unopened at the recommended temperature herein. Product warranties for this reference material are set out in the terms and conditions of purchase.

Intended Use

This RM is intended for use in a laboratory as a calibration and quality control standard or in method development for analytical techniques.

Safety

Proper precautions should be observed while handling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements are calibrated with weights traceable to the national standards (DKD). The calibration of the balances is verified daily internally and annually by an external accredited calibration service. Chromatographic methods are traceable to the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RM have been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealed container at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum sample size and if less material is used, to increase the certified uncertainty by a factor of two for half sample and four for a quarter of sample. If storage after opening is necessary, the RM should be tightly closed and kept from light and moisture. If the RM was in a sealed ampoule, it should be transferred to a vial with minimum head space.

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标准名称及标准号
GB 23200.113-2018 食品安全国家标准 植物源性食品中百菌清等农药残留量的测定 气相色谱-质谱法》
适用范围
适用于蔬菜、水果、谷物、茶叶等植物源性食品中百菌清残留量的测定。
核心检测方法
采用气相色谱-质谱法(GC-MS),样品经乙腈提取,固相萃取柱净化,氮吹浓缩后进样分析。
检出限与定量限
检出限为0.005 mg/kg,定量限为0.01 mg/kg。
质控样品要求
每批次样品需包含空白对照、加标回收样品(加标浓度0.01-0.1 mg/kg),回收率应控制在70%-120%,相对标准偏差(RSD)≤15%。
关键实验步骤
1. 样品均质后乙腈振荡提取;
2. 盐析分层后取上清液过SPE柱净化;
3. 氮吹至近干后用丙酮定容;
4. GC-MS分析,外标法定量。
特别说明
该方法需注意基质效应对定量结果的影响,必要时采用基质匹配标准曲线校准。若样品色素干扰严重,需增加净化步骤。
标准名称及标准号
GB/T 20769-2008 水果和蔬菜中450种农药及相关化学品残留量的测定 液相色谱-串联质谱法》
适用范围
涵盖百菌清在内的多种农药残留检测,适用于果蔬样品。
核心检测方法
QuEChERS前处理结合LC-MS/MS分析,乙腈提取后经PSA和C18吸附剂净化。

以上信息仅供参考,请以相应标准的原文为准!