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氯菊酯(EC 17025)_52645-53-1,氯菊酯
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氯菊酯(EC 17025)

BW902016 {{goodObj.price > 0 ? '¥' + goodObj.price : '咨询'}} ¥{{goodObj.sell_price || 0}} 咨询 52645-53-1 100mg {{goodObj.date}} 秦境标物 {{item.norm}} 97.2% {{inventory}}
氯菊酯介绍:

Reference Material

This certificate is designed in accordance with ISO17034 and ISO Guide 31. This reference material (RM) was designed,produced andverified in accordance with ISO/IEC 17025, ISO 17034 and a registered qualitymanagement system ISO9001.

Product Name

Permethrin

Product Code

BW902016

Lot Number

23051517

CAS No.

52645-53-1

Mol. Formula

C21H20Cl2O3

Mol. Weight

391.29

Certified on

26 May 2023

Expiry Date

25 May 2025

Storage Temp

20°C ± 4°C

Specification

100 mg


CERTIFIED

Purity

CERTIFIED

Expanded Uncertainty (U)

Approved by

97.2%

0.5%

Method of Characterisation

GC/FID

Batch Information

Water Content: <0.1% (by Karl-Fischer-Titration)

Uncertainty

The certified value(s) and uncertainty(ies) aredetermined in accordance with ISO 17034 with an 95% confidence level (k=2).Uncertainty is based on the Total Combined Uncertainty, including uncertaintiesof characterisation, homogeneity and stability testing. Stability values arebased on real evidence opposed to simulation.


The producer certifies that this reference materialmeets the specification stated in this certificate until the expiry date,provided it is stored unopened at the recommended temperature herein. Productwarranties for this reference material are set out in the terms and conditionsof purchase.


Intended Use

This RM is intended for use in a laboratory as acalibration and quality control standard or in method development foranalytical techniques.

Safety

Proper precautions should be observed whilehandling. See Safety Data Sheet.

Traceability

The balances used for gravimetric measurements arecalibrated with weights traceable to the national standards (DKD). Thecalibration of the balances is verified daily internally and annually by anexternal accredited calibration service. Chromatographic methods are traceableto the International System of Units (SI).

Homogeneity

Random replicate samples of the final packaged RMhave been analysed to prove homogeneity compliant with ISO 17034.

Storage

The RM should be stored in the original sealedcontainer at the indicated temperature.

Instructions for use

It is recommended to use 1 mg as the minimum samplesize and if less material is used, to increase the certified uncertainty by afactor of two for half sample and four for a quarter of sample. If storageafter opening is necessary, the RM should be tightly closed and kept from lightand moisture. If the RM was in a sealed ampoule, it should be transferred to avial with minimum head space.


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国家标准解读: 食品安全国家标准 植物源性食品中氯菊酯残留量的测定 气相色谱-质谱法
标准名称及标准号GB 23200.113-2018
适用范围适用于植物源性食品(蔬菜、水果、谷物等)中氯菊酯残留量的测定,定量限为0.01 mg/kg。
核心检测方法样品经乙腈提取,固相萃取柱净化后,采用气相色谱-质谱法(GC-MS)检测,外标法定量。
检出限与定量限检出限(LOD)为0.003 mg/kg;定量限(LOQ)为0.01 mg/kg。
质控样品要求需包含空白样品、加标回收率样品(添加浓度为LOQ至10倍LOQ范围),平行样检测偏差≤20%。
关键实验步骤1. 均质化样品后超声辅助提取;
2. 采用C18或等效固相萃取柱净化;
3. GC-MS分析参数:色谱柱为HP-5MS(30 m×0.25 mm×0.25 μm),进样口温度250℃,分流比10:1。
特别说明需注意基质效应对定量结果的影响,必要时采用基质匹配标准曲线校正。
行业标准解读:HJ 863-2017 环境空气 颗粒物中氯菊酯的测定 高效液相色谱法
标准名称及标准号HJ 863-2017
适用范围适用于环境空气及污染源废气中颗粒态氯菊酯的测定,定量下限为0.05 μg/m³(采样体积500 L)。
核心检测方法颗粒物样品经石英纤维滤膜采集,索氏提取法富集后,采用高效液相色谱法(HPLC)分析。
检出限与定量限方法检出限(MDL)为0.005 μg/m³;测定下限为0.02 μg/m³。
质控样品要求每批次样品需做实验室空白、运输空白及加标平行样,加标回收率范围为70%-120%。
关键实验步骤1. 采样流速控制(100 L/min),避免滤膜过载;
2. 提取溶剂为二氯甲烷,浓缩后定容至1.0 mL;
3. HPLC分析参数:C18色谱柱(4.6×250 mm, 5 μm),流动相为甲醇-水(85:15),检测波长230 nm。
特别说明采样过程中需避免滤膜破损,防止气相态目标物吸附损失。
其他相关标准: 动物肌肉中氯菊酯残留量的测定
标准名称及标准号GB/T 20772-2006
适用范围适用于猪、牛、禽类等动物肌肉组织中氯菊酯残留量的测定,定量限为0.01 mg/kg。
核心检测方法样品经乙酸乙酯振荡提取,凝胶色谱净化后,气相色谱法(ECD检测器)定量分析。
检出限与定量限检出限为0.003 mg/kg;定量限为0.01 mg/kg。
质控样品要求每批次需检测阳性对照样品,结果相对偏差≤15%。
关键实验步骤1. 样品均质后高速离心分离脂肪;
2. 凝胶色谱参数:Bio-Beads S-X3填料,流动相为环己烷-乙酸乙酯(1:1);
3. GC-ECD分析:HP-5色谱柱(30 m×0.32 mm×0.25 μm),进样口温度250℃,检测器温度300℃。
特别说明需注意脂肪残留对检测结果的干扰,必要时进行二次净化。

以上信息仅供参考,请以相应标准的原文为准!